Difference between revisions of "NOy PEG"

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All plots from this run can be found here: {{pdf|RatesRemoved_xlbqb.pdf|RatesRemoved_xlbqb.pdf}}
 
All plots from this run can be found here: {{pdf|RatesRemoved_xlbqb.pdf|RatesRemoved_xlbqb.pdf}}
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Zonal-mean tendency plots can be found here: {{pdf|RatesRemoved_xlbqb_NOy_UKCA_tendency.pdf|RatesRemoved_xlbqb_NOy_UKCA_tendency.pdf}}
   
 
===16. Rates of NOy bimolecular interconversion reactions were set to zero===
 
===16. Rates of NOy bimolecular interconversion reactions were set to zero===

Revision as of 12:30, 24 April 2015

vn7.3 vs. vn8.4

While UKCA had low NOy at vn7.3, this feature has not improved when moving to vn8.2/vn8.4 GA4.0 jobs, and may even have become worse.

A pair of simulations have been set-up to try to aid the diagnosis of the cause of this low NOy. While there have been many changes to the base atmospheric model, the differences between the UKCA chemistry scheme used have been minimised.

  • All surface and aircraft chemical emissions are the same between both jobs, and are year 2000 climatologies
  • The SST/Sea-Ice ancillaries are daily means from the Reynolds dataset, and are meaned over 1995-2005
  • All chemical reactions and associated rates are the same between both jobs
  • The GHGs and tracer lower boundary conditions are the same for both jobs
    • 2000-12-01 from the CCMI REF-C2 specification taking WMO2011 values for ODSs and following the historical values for GHGs from the RCP scenarios defined for CMIP5
  • The initial conditions of the chemical species are the same for both jobs, originally taken from a vn7.3 job. The winds and other physical initial conditions are different however
  • Radiative feedback from O3 is included in both jobs
    • vn8.4 job also considers radiative feedback from aerosols
  • The same lightning NOx routine were used by both models, and these were scaled to give approximately the same annual emissions

NOTE: While the vn8.4 job does include GLOMAP-mode aerosols and some extra associated chemical reactions, the low NOy has also been observed in the vn8.2 CheST (only) configuration.

Results

VN7.3 VN8.4 VN7.3
MONSooN jobid xjcir xjcin xgywn
Configuration HadGEM3-A r2.0 HadGEM3-A GA4.0 HadGEM3-A r2.0 (ish)
Resolution N48L60 N96L85 N48L60
UKCA scheme CheST CheST+GLOMAP CheST
Model set-up TS2000 TS2000 TS2000
Evaluation Suite Output (Chemistry)

Pdficon small.png Xjcir_eval_yr01.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr02.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr03.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr04.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr05.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr06.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr07.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr08.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr09.pdf Info circle.png
Pdficon small.png Xjcir_eval_yr10.pdf Info circle.png

Pdficon small.png Xjcin_eval_yr01.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr02.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr03.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr04.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr05.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr06.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr07.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr08.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr09.pdf Info circle.png
Pdficon small.png Xjcin_eval_yr10.pdf Info circle.png

Evaluation Suite Output (Aerosol)

N/A

Pdficon small.png Xjcin_EvalAero_yr01.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr02.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr03.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr04.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr05.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr06.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr07.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr08.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr09.pdf Info circle.png
Pdficon small.png Xjcin_EvalAero_yr10.pdf Info circle.png

NOy species time evolution Pdficon small.png Xjcir_NOy.pdf Info circle.png Pdficon small.png Xjcin_NOy_yr01-06.pdf Info circle.png
Comparison with SLIMCAT Pdficon small.png Compare_SLIMCAT_UKCA.pdf Info circle.png
Stratospheric Flux Analyis Pdficon small.png strat_output.pdf Info circle.png
Lightning NOx

year 01 4.31451 Tg(N)/year
year 02 4.14917 Tg(N)/year
year 03 4.16817 Tg(N)/year
year 04 4.17091 Tg(N)/year
year 05 4.21050 Tg(N)/year
year 06 4.15449 Tg(N)/year
year 07 4.24399 Tg(N)/year
year 08 4.16796 Tg(N)/year
year 09 4.25567 Tg(N)/year
year 10 4.19239 Tg(N)/year

year 01 3.93965 Tg(N)/year
year 02 3.94823 Tg(N)/year
year 03 4.00135 Tg(N)/year
year 04 4.00217 Tg(N)/year
year 05 3.96633 Tg(N)/year
year 06 3.92943 Tg(N)/year
year 07 4.02144 Tg(N)/year
year 08 3.82724 Tg(N)/year

NB The stratospheric analysis pdf file contains a table of the annual sum throughout the stratosphere (moles /yr) for all reactions that produce or destroy a chemical species in the run. The pdf is sorted alphabetically (Br first PPAN at the end).

Minutes from meeting 2014-02-13

Present
Luke Abraham (NLA), Alex Archibald, James Keeble (JMK), Sandip Dhomse, Paul Griffiths, Martyn Chipperfield, John Pyle, Fiona O'Connor (skype)
Further experiments suggested
  1. Change how the NOy species are treated: removed these from transform_halogen and make a new routine which also requires NO2 to be transported. The NOy (i.e. Lumped N) tracer is also advected and this is used as a test against the calculated NOy field from the individual species. Using this comparison the NOy species can be rescaled according to the ratio of and . BrONO2 and ClONO2 should not be rescaled as this would change the Cl and Br species. A diagnostic check on the differences between and should be done, as well as possibly checking for global conservation during transport. The NALD tracer is not currently included and should be. (NLA to do)
  2. Further to the above, try turning off all other processes and check the advection over a short run. Other steps could then be added piecewise to see their effects.
  3. Check that N2O5 is not causing any problems by setting its rates to zero and set it to no_change in transform_halogen (JMK to do)

Sensitivity tests

NLA has performed several sensitivity tests following the meeting and the recommendations above.

Note that for the plots below, NOy was calculated by summing up all the other species in post-processing.

An example of the problem is:

Xkawa HNO3.png

Changes required to below plots

The plots below are rather confusing, and there are a lot of them. The following changes will be made, but unfortunately not for the teleconference on the 15th December:

  1. Change the units so that all species are plotted in kg(N). Currently all plots are in kg(Species) except for NOy.
  2. Include the initial value from the .astart file in the plots, to give the initial condition. This should highlight some of the strange behaviour in NOy.

The results from these tests are:

1. transform_nitrogen routine

The NOy components of transform_halogen were removed, and implemented in a separate routine. Now, NO2 and lumped NOy are also advected and instead of NO2 being the residual instead a calculated_NOy field is computed from the separately advected NOy species, and this is compared to the transported_NOy field. The differences here are then used to tweak the NOy species that all allowed to be changed by the routine (currently, not ClONO2 and BrONO2). This is job xjcis.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N).

Base NOy.png

The model is still spinning up slightly from the initial condition.

All plots from this run can be found here: Pdficon small.png Base_xjcis.pdf Info circle.png

2. Doubled HNO3

A copy of xjcis (and so transform_nitrogen was still used) was taken and the HNO3 initial condition was doubled (contribution also included in NOy) to bring the values up to what should be expected. This is job xjcit.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N), and the shorter x-axis.

HNO3x2 NOy.png

The run was stop after only a few years as the HNO3 mass dropped rather quickly. The NOy mass also drops.

All plots from this run can be found here: Pdficon small.png HNO3x2_xjcit.pdf Info circle.png

3. No production or loss of any NOy species

A copy of xjcit was taken (i.e. including the doubled HNO3 initial condition and using tranform_nitrogen). All sources and sinks of any NOy species were removed, i.e. no deposition, emissions, or sedimentation. All reactions were still included if they interconverted between NOy species, but any reactions which produced or removed NOy were not included. This is job xjciv.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N).

NoSourceSink NOy.png

There is some interesting structure in the evolution of several of the species. These can be highlighted if required. While a lot of the species seem to have an exponential decay, others do not.

All plots from this run can be found here: Pdficon small.png NoSourceSink_xjciv.pdf Info circle.png

Alex has also done some additional analysis: Pdficon small.png Xjciv_NOy_chem.pdf Info circle.png

4. No calls to any UKCA routines

A copy of xjciv was taken (including the doubled HNO3 initial condition), and calls to the transform_halogen/nitrogen, fastjx, emission_ctl, chemistry_ctl, and aero_ctl routines were removed. This is job xkqhb.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N), and the shorter x-axis.

NoEmsChemAero NOy.png

This is as expected. The tracer transport scheme should be globally mass conserving, and it is. If it were not we would have had a bigger problem! This test also confirms that the problem is contained within UKCA itself.

All plots from this run can be found here: Pdficon small.png NoEmsChemAero_xkqhb.pdf Info circle.png

5. Call to ukca_emission_ctl only

A copy of xkqhb was taken (including the doubled HNO3 initial condition), and call to emission_ctl was included again (there were still no calls to the transform_halogen/nitrogen, fastjx, chemistry_ctl, and aero_ctl). Note that there were no emissions into any of the NOy species in this run. This is job xkqhc.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N), and the shorter x-axis.

EmsOnly NOy.png

As well as showing that the emission_ctl routine isn't causing the problem, this also shows that it isn't coming from boundary layer mixing, either, as this is done in emission_ctl for the section 34 (UKCA) tracers.

All plots from this run can be found here: Pdficon small.png EmsOnly_xkqhc.pdf Info circle.png

6. Call to transform_halogen and transform_nitrogen only

A copy of xkqhb was taken (including the doubled HNO3 initial condition), and the forward and backward calls to transform_halogen and transform_nitrogen were included again (there were still no calls to the emission_ctl fastjx, chemistry_ctl, and aero_ctl). This is job xkqhd.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N), and the shorter x-axis.

TransOnly NOy.png

There are some corrections to the NOy species initially (these probably go down as the horizontal gradients are smoothed out during the run). However, NOy remains mostly constant and does not drop by very much.

All plots from this run can be found here: Pdficon small.png TransOnly_xkqhd.pdf Info circle.png

7. Call to transform_halogen, transform_nitrogen, and chemistry_ctl only

A copy of xkqhd was taken (including the doubled HNO3 initial condition), and, as well as the forward and backward calls to transform_halogen and transform_nitrogen, the call to chemistry_ctl was included again (there were still no calls to the emission_ctl fastjx, and aero_ctl). While FastJX was not used (the rates from this routine were set to zero), there is still a contribution to the photolysis rates from the lookup table scheme in the upper levels of the model. This is job xkqhe.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N), and the shorter x-axis.

TransChemOnly NOy.png

There should be changes to the NOy species, which may involve them increasing or decreasing during the course of the run. The important thing here is that NOy changes as well.

As there is no photolysis or emissions, the evolution is different from the original no sources or sinks run. This implies that the problem is in chemistry_ctl, or in the combination of chemistry_ctl and transform_nitrogen.

Looking at the figures below for NOy and N2O5 in more detail, it appears that the drop in both is highly correlated (after the first few months), more-so than with other species. Note the different scales on the y-axis.

Also, the initial mass of NOy seems around 25% higher in this run than in the other runs, despite the fact that they all started from the same initial condition. It is unclear why the value is higher here.

Xkhqe NOy.pngXkhqe N2O5.png

All plots from this run can be found here: Pdficon small.png TransChemOnly_xkqhe.pdf Info circle.png

8. Call to transform_halogen and chemistry_ctl only

A copy of xkqhe was taken (including the doubled HNO3 initial condition), and the calls to transform_nitrogen were removed. The forward and backward calls to transform_halogen and chemistry_ctl were still included (there were still no calls to the emission_ctl fastjx, and aero_ctl). The photolysis rates were completely set to zero in this simulation. This is job xkqhf.

The image below shows the evolution of the total atmospheric mass of each of the NOy species, in kg(species). Note that NOy is given in kg(N), and the shorter x-axis.

ChemOnly NOy.png

As above (xkqhe), there should be changes to the NOy species, which may involve them increasing or decreasing during the course of the run. The important thing here is that NOy changes as well.

As there is no photolysis or emissions, the evolution is different from the original no sources or sinks run. Given that transform_nitrogen is not called in this run, this implies that the problem is in chemistry_ctl alone, and is not associated with photolysis.

Looking at the figures below for NOy and N2O5 in more detail, it appears that the drop in both is still highly correlated (after the first few months), more-so than with other species. Note the different scales on the y-axis.

Also, the initial mass of NOy still seems around 25% higher in this run than in the other runs, despite the fact that they all started from the same initial condition. It is unclear why the value is higher here, but it is not associated with transform_nitrogen.

Xkhqf NOy.pngXkhqf N2O5.png

All plots can be found here: Pdficon small.png ChemOnly_xkqhf.pdf Info circle.png

9. Call to transform_halogen and chemistry_ctl (with no call to asad_trimol) only

A copy of xkqhf was taken (including the doubled HNO3 initial condition). The forward and backward calls to transform_halogen and chemistry_ctl were still included (there were still no calls to the transform_nitrogen, emission_ctl fastjx, and aero_ctl). The photolysis rates were completely set to zero in this simulation. The call to asad_trimol was commended out in asad_cdrive, which means that there will be no termolecular reactions at all in this simulation. This is job xkqhg.

NoTrimol NOy.png

Xkhqg NOy.pngXkhqg N2O5.png

All plots from this run can be found here: Pdficon small.png NoTrimol_xkqhg.pdf Info circle.png

10. Call to transform_halogen and chemistry_ctl (with no call to hetero routines) only

A copy of xkqhg was taken (including the doubled HNO3 initial condition). The forward and backward calls to transform_halogen and chemistry_ctl were still included (there were still no calls to the transform_nitrogen, emission_ctl fastjx, and aero_ctl). The photolysis rates were completely set to zero in this simulation. The call to asad_trimol was put back in in asad_cdrive, but all heterogeneous routines in asad_cdrive were commented out. This is job xkqhh.

NoHetero NOy.png

Xkqhh NOy.pngXkqhh N2O5.png

All plots from this run can be found here: Pdficon small.png NoHetero_xkqhh.pdf Info circle.png

11. Call to transform_halogen and chemistry_ctl (with no call to ukca_wetdep) only

A copy of xkqhh was taken (including the doubled HNO3 initial condition). The forward and backward calls to transform_halogen and chemistry_ctl were still included (there were still no calls to the transform_nitrogen, emission_ctl fastjx, and aero_ctl). The photolysis rates were completely set to zero in this simulation. The calls to the heterogeneous routines in asad_cdrive were put back in, but the call to ukca_wetdep was commented out, meaning that there will be no wet deposition of any species. This is job xkqhi.

NoWetDep NOy.png

Xkqhi NOy.pngXkqhi N2O5.png

All plots from this run can be found here: Pdficon small.png NoWetDep_xkqhi.pdf Info circle.png

12. Call to transform_halogen and chemistry_ctl (with no call to ukca_drydep) only

A copy of xkqhi was taken (including the doubled HNO3 initial condition). The forward and backward calls to transform_halogen and chemistry_ctl were still included (there were still no calls to the transform_nitrogen, emission_ctl fastjx, and aero_ctl). The photolysis rates were completely set to zero in this simulation. The call to ukca_wetdep in asad_cdrive was put back in, but the call to ukca_drydep was commented out, meaning that there will be no wet deposition of any species. This is job xkqhj.

NoDryDep NOy.png

Xkqhj NOy.pngXkqhj N2O5.png

All plots from this run can be found here: Pdficon small.png NoDryDep_xkqhj.pdf Info circle.png

Planned Tests

There are a number of planned tests:

  1. Double N2O+(O1D) rate as done at vn7.3
  2. Run the NoSourceSink (xjciv) in 2 new ways:
    1. Set all rates of NOy involved reactions to zero
    2. Remove all NOy involved reactions

The latter two should give equivalent results, assuming that there is no overwriting being done in asad_bimol or asad_trimol.

New Results

A number of others tests were run, listed below. When plotting these, it was realised that the NO2 contribution had not been included in the original plots above - this has now been corrected.

13. No call to conserve

A copy of xjciv was taken (including the doubled HNO3 initial condition). The call to the conserve routine was removed. This is job xkqha.

NoConserve NOy.png

All plots from this run can be found here: Pdficon small.png NoConserve_xkqha.pdf Info circle.png

14. NOy interconversion reaction rates set to zero

A copy of xjciv was taken (including the doubled HNO3 initial condition). The rates of all NOy interconversion reactions in ukca_chem_strattrop were set to zero. This is job xlbqa.

RatesToZero NOy.png

All plots from this run can be found here: Pdficon small.png RatesToZero_xlbqa.pdf Info circle.png

One of the dependent reactions was still in place, but this does not affect the NOy conservation.

15. NOy interconversion reactions removed

A copy of xjciv was taken (including the doubled HNO3 initial condition). All NOy interconversion reactions in ukca_chem_strattrop were removed. This is job xlbqb.

RatesRemoved NOy.png

All plots from this run can be found here: Pdficon small.png RatesRemoved_xlbqb.pdf Info circle.png

Zonal-mean tendency plots can be found here: Pdficon small.png RatesRemoved_xlbqb_NOy_UKCA_tendency.pdf Info circle.png

16. Rates of NOy bimolecular interconversion reactions were set to zero

A copy of xjciv was taken (including the doubled HNO3 initial condition). All NOy bimolecular interconversion reactions in ukca_chem_strattrop were set to zero (i.e. there were only termolecular reactions). This is job xlbqd.

BimolZero NOy.png

All plots from this run can be found here: Pdficon small.png BimolZero_xlbqd.pdf Info circle.png

17. Rates of NOy bimolecular interconversion reactions were set to zero and the special reactions were removed

A copy of xjciv was taken (including the doubled HNO3 initial condition). All NOy bimolecular interconversion reactions in ukca_chem_strattrop were set to zero (i.e. there were only trimolecular reactions) and the special trimolecular reactions in asad_trimol were removed. This is job xlbqf.

BimolZeroNoDep NOy.png

All plots from this run can be found here: Pdficon small.png BimolZeroNoDep_xlbqf.pdf Info circle.png

18. Rates of NOy trimolecular interconversion reactions were set to zero

A copy of xjciv was taken (including the doubled HNO3 initial condition). All NOy trimolecular interconversion reactions in ukca_chem_strattrop were set to zero (i.e. there were only bimolecular reactions). This is job xlbqc.

TrimolZero NOy.png

All plots from this run can be found here: Pdficon small.png TrimolZero_xlbqc.pdf Info circle.png

19. Rates of NOy trimolecular interconversion reactions were set to zero and the NOy special reactions were removed

A copy of xjciv was taken (including the doubled HNO3 initial condition). All NOy trimolecular interconversion reactions in ukca_chem_strattrop were set to zero (i.e. there were only bimolecular reactions) and the special termolecular reactions in asad_trimol were removed. This is job xlbqe.

TrimolZeroNoDep NOy.png

All plots from this run can be found here: Pdficon small.png TrimolZeroNoDep_xlbqe.pdf Info circle.png

20. Solver and timestep changes

A copy of xjciv was taken (including the doubled HNO3 initial condition). The chemical timestep was changed to 20 minutes (rather than 1 hour), the value of rafeps was made smaller and maxneg was set to zero. This is job xlbqg.

SolverChanges NOy.png

All plots from this run can be found here: Pdficon small.png SolverChanges_xlbqg.pdf Info circle.png

Further xjciv analysis

ATA has performed further analysis on the xjciv simulation (where the production and loss of NOy was removed) looking at the zonal-mean loss rate of NOy. The results are very interesting:

These point to a tropospheric loss, possibly associated with aerosol?

Xjciv NOy chem p12.png

Summary of runs to date

The following plot gives a summary of the runs to date, with the initial value of NOy also included.

AllNOy 20.png

Tests planned

Following the teleconference on 2015-03-03, the following further tests/analysis were suggested:

Present: Luke Abraham (LA), Alex Archibald (AA), John Pyle (JP), Paul Griffiths (PG), James Keeble (JK), Martyn Chipperfield (MC), Sandip Dhomse (SD), Fiona O'Connor (FOC).

  • Make sure asad_hetero is not called
  • Check for any processes at 19km - extremely useful given the fact that the losses seem to occur below this height
  • Do the zonal-mean diagnostics again for expt 15.
  • Check the N2O5+M reaction in asad_trimol
  • Either Build up NOy complexity from the ground up or try removing various NOy species (and associated reactions) from the solver instead
    • it was decided to do 3 runs:
      1. remove N2O5
      2. remove HONO2
      3. remove both N2O5 and HONO2
  • SD may be able to look at Zonal mean plots
  • LA to set up a doodle poll for Mon 23rd/Tue 24th - done: http://doodle.com/zc2zguhgitatd7az

Role of TR_MIX

Two short test jobs were run: xlbqh which includes the call to TR_MIX; and xlbqi which had the calls to TR_MIX commented out.

These runs were based on xlbqb (expt. 15) which had the NOy reactions removed from the chemistry specification.

A lot of the structure in the troposphere, and the hard-line at ~17km/level 50 comes from this call to TR_MIX.

Call to TR_MIX included Call to TR_MIX commented out

21. TR_MIX and ASAD_HETERO not called

A copy of xjciv was taken (including the doubled HNO3 initial condition). The calls to TR_MIX and ASAD_HETERO were removed. This is job xlbqm.

NoTRMIX NOy.png

All plots from this run can be found here: Pdficon small.png NoTRMIX_xlbqm.pdf Info circle.png

Zonal-mean tendency plots can be found here: Pdficon small.png NoTRMIX_xlbqm_NOy_UKCA_tendency.pdf Info circle.png

22. N2O5 reactions removed

A copy of xlbqm was taken (including the doubled HNO3 initial condition). All remaining reactions involving N2O5 were removed. This is job xlbqj.

NoN2O5 NOy.png

All plots from this run can be found here: Pdficon small.png NoN2O5_xlbqj.pdf Info circle.png

Zonal-mean tendency plots can be found here: Pdficon small.png NoN2O5_xlbqj_NOy_UKCA_tendency.pdf Info circle.png

23. HNO3 reactions removed

A copy of xlbqm was taken (including the doubled HNO3 initial condition). All remaining reactions involving HNO3 were removed. This is job xlbqk.

NoHONO2 NOy.png

All plots from this run can be found here: Pdficon small.png NoHONO2_xlbqk.pdf Info circle.png

Zonal-mean tendency plots can be found here: Pdficon small.png NoHONO2_xlbqk_NOy_UKCA_tendency.pdf Info circle.png

23. N2O5 and HNO3 reactions removed

A copy of xlbqm was taken (including the doubled HNO3 initial condition). All remaining reactions involving N2O5 and HNO3 were removed. This is job xlbql.

NoN2O5orHONO2 NOy.png

All plots from this run can be found here: Pdficon small.png NoN2O5orHONO2_xlbql.pdf Info circle.png

Zonal-mean tendency plots can be found here: Pdficon small.png NoN2O5orHONO2_xlbql_NOy_UKCA_tendency.pdf Info circle.png

Comparison of xjciv, xlbqm, xlbqj, xlbqk, & xlbql

AllNOy N2O5HONO2.pngAllNOy N2O5HONO2 Y.png

The second image also includes the Base (xjcis) and 2xHNO3 (xjcit) runs for comparison. In these, both xjcis and xjcit have all processes on.

Tracers totals after various UKCA routines

The images below show output from xlbqo (a copy of xlbqm: no TR_MIX or ASAD_HETERO) which includes a UKCA_DEBUG_TRACERS routine, which can diagnose the change in UKCA chemical tracers due to each suboutine (or the rest of the UM as a whole):

Ukca debug tracers.pngXlbqo ukca debug tracers.png

Lines are for NOy unless otherwise stated.

The images below show how the various NOy species are affected by UKCA_CHEMISTRY_CTL:

Chem debug tracers.pngXlbqo chem debug tracers.png

Note that these show the change global total mass of each tracer. Information is available for all tracers, in kg and in % change. The first image in each set are just for the 1st day of the run, the second is for around 8.5 days of run (the UKCA_DEBUG_TRACERS slows the model down considerably, so this run hit the 3-hour wallclock limit).

Suggested Further Tests (2015-04-13)

  1. Adjust the above % change plots by having a MetUM, UKCA_CHEMISTRY_CTL and "the bit between the MetUM and UKCA_CHEMISTRY_CTL" and "the bit between UKCA_CHEMISTRY_CTL and the MetUM".
  2. Extend the UKCA_DEBUG_TRACERS routine so that it can work around all the different subroutines called from within UKCA_CHEMISTRY_CTL (possibly an ASAD_DEBUG_TRACERS). This will probably have to contain level-by-level information due to the way ASAD is called.
  3. Repeat the tests which commented out the various types of reactions (and also extend this to individual reactions) and run these with these DEBUG_TRACERS routines on to try to assess the impact of each reaction type.

24. N2O5+H2O->2HNO3 reaction removed

A copy of xlbqm was taken (including the doubled HNO3 initial condition). All the reaction was removed. The only two reactions that remain are:

This is job xlbqn.

NoB085 NOy.png

All plots from this run can be found here: Pdficon small.png NoB085_xlbqn.pdf Info circle.png

Zonal-mean tendency plots can be found here: Pdficon small.png NoB085_xlbqn_NOy_UKCA_tendency.pdf Info circle.png

The comparison plot has also been updated, showing the impact of this reaction's removal as compared to the more recent tests.

AllNOy B085.png

NOy telecon minutes 2015-04-14 2pm-3pm

Present: LA, JP, PG, AA, JK, MC

Please see also the results of the B085 reaction

being removed above (test 24), which were only added after the meeting.

Suggestions:

  1. Check effects of TR_MIX and ASAD_HETERO independently (c.f. xlbqm - blue line).
  2. Try changing the rates of the fast N2O5 termolecular reactions to slow them down and seeing what effect this has.
  3. Put the UKCA_DEBUG_TRACERS call around the UKCA_TRANSFORM_NITROGEN routine.
  4. Try comparing (e.g. the zonal-mean tendencies) to another, separate tracer, e.g. CH4, with the prod and loss reactions changed accordingly.
    • This may need to be tested with a pair of interconverted tracers.
  5. Create ZM plots showing mass/moles of NOy, to find where it is most abundant.
  6. Double-check how the zonal-mean tendencies are calculated, and make sure that there aren't any mistakes.
  7. Change the N2O5 termolecular reactions to:
    with the rates adjusted accordingly. Do this in a run which has B085 removed, leaving these as the only N2O5 reactions and then compare to xlbqn.
  8. Look into what debugging settings/options are available in the solver.
  9. Redo the Base run (xjcis) to remove all the N2O5 reactions and see how this looks.

MC suggested that we should try to not lose sight of the original problem. It would be a good idea for the Base run (xjcis) to be included in all comparison plots, as well as bringing suggested ideas back to be run in the Base (c.f. xjcis) configuration.